Preparation of monodisperse silica particles: control of size and mass fraction

GH Bogush, MA Tracy, CF Zukoski Iv - Journal of non-crystalline solids, 1988 - Elsevier
GH Bogush, MA Tracy, CF Zukoski Iv
Journal of non-crystalline solids, 1988Elsevier
We extend the work of Stober, Fink and Bohn (J. Colloid Interfac Sci. 26 (1968) 62) to
establish the ranges of reagent concentrations which result in the precipitation of
monodisperse silica particles from ethanol solutions containing ammonia, water, and
tetraethyl orthosilica. A correlation is presented which can be used to predict final particle
sizes over concentrations of 0.1-0.5 M TEOS, 0.5–17.0 MH 2 O and 0.5-3 M NH 3. The
maximum particle size achievable for these conditions at 25° C is⋍ 800 nm and near the …
Abstract
We extend the work of Stober, Fink and Bohn (J. Colloid Interfac Sci. 26 (1968) 62) to establish the ranges of reagent concentrations which result in the precipitation of monodisperse silica particles from ethanol solutions containing ammonia, water, and tetraethyl orthosilica. A correlation is presented which can be used to predict final particle sizes over concentrations of 0.1-0.5 M TEOS, 0.5–17.0 M H2O and 0.5-3 M NH3. The maximum particle size achievable for these conditions at 25°C is ⋍ 800 nm and near the maximum, monodispersity is difficult to maintain. The effects of reaction temperature are studied and particle size distributions are analyzed. A seeded growth technique for preparing larger particles and/or increasing solids mass fraction up to a theoretical limit of ⋍ 24 wt% of silica is described.
Elsevier